Refrigeration Applications - OxyChem Calcium Chloride
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Refrigeration

Calcium chloride refrigerating brines are highly effective for use in ice rinks and other low-temperature applications. Used as a secondary coolant, the solution provides continuous chilling.

ice rink - refrigeration - OxyChem calcium chloride
child ice skating on an ice rink - refrigeration - OxyChem calcium chloride

Where To Use

With a freeze point as low as -60°F, solutions made from calcium chloride are highly effective refrigerating brines used in ice rinks and other low-temperature applications. Calcium chloride is used as a secondary coolant, chilling the ice or refrigerated surface. Within a closed, continuous loop, the brine is chilled to provide cooling to the refrigerated surface. Then, the brine returns to be rechilled and the cycle is repeated.

Recommended Products

Refrigeration FAQs

First, determine the amount of dry calcium chloride to mix with water using our helpful Making Solutions Calculator tool.

Always start with cool water and add the solid calcium chloride slowly to the water while continuously mixing. Significant heat is released when dissolving solid calcium chloride, and a temperature increase will occur. For example, when dissolving DOWFLAKE®  Xtra 83-87% Calcium Chloride Flakes while making up a 30% solution, the temperature can be expected to increase almost 84°F.

If solids are allowed to sit motionless while in contact with water, a hard cake will form that will be slow to dissolve.

Please consult our Diluting Solutions Calculator, which covers three different options:

  1. Diluting with water
  2. Diluting with a lower concentration calcium chloride solution
  3. Diluting with both water and a lower concentration calcium chloride solution

The pH reading for an undiluted sample of 35% solution is approximately 9. OxyChem calcium chloride products are alkaline due to the presence of a slight calcium hydroxide impurity.

Accurate and consistent pH measurement in concentrated salt solutions can be challenging. Results vary depending on the pH probe used and the degree of sample dilution.

No, OxyChem does not have a calcium chloride dihydrate product. DOWFLAKE® Xtra is the closest to a dihydrate concentration.

Calcium chloride dihydrate has two water molecules for every one calcium chloride molecule, giving an overall calcium chloride concentration of 75.5%. OxyChem’s DOWFLAKE® Xtra product contains a minimum of 83% calcium chloride, making it more concentrated than the calcium chloride dihydrate flake on the market. 

Store product in a dry area, and tightly reseal after each use. To maintain product quality while in storage, solid calcium chloride must be protected from moisture. If the product is on a pallet covered by an intact plastic shroud, it can be stored outdoors on a well-drained surface. If the shroud is torn, pierced, or removed, the palletized product should be stored indoors or under a waterproof covering.

For additional information, see our Calcium Chloride Handbook.

When properly stored to protect from moisture contact, the expected shelf life for solid calcium chloride products is 36 months from the date of manufacture. Calcium chloride does not degrade or deteriorate; however, the shelf life is limited based on the potential for moisture intrusion into the product, which may cause product clumping. Solid calcium chloride absorbs moisture from the air (i.e., is hygroscopic), even to the point of converting to liquid brine (i.e., is deliquescent).

Technical grades of solid and liquid calcium chloride may be used to freeze-proof water-filled containers, such as traffic barriers. The target concentration depends primarily on the level of freeze protection desired. See below for the freeze points of typical concentrations. Use our helpful Making Solutions Calculator tool to determine the amount of dry calcium chloride to mix with water to achieve solutions of various concentrations.

Freeze Points of Typical Calcium Chloride Concentrations

Percentage by Weight

Specific Gravity

lbs/gal

Freeze Point

16 wt%

1.149

9.55

+8°F

20 wt%

1.189

9.88

-4°F

24 wt%

1.228

10.20

-20°F

28 wt%

1.275

10.60

-46°F

32 wt%

1.322

10.99

17°F

Freeze Points of Typical Calcium Chloride Concentrations
16 wt%

Specific Gravity

1.149

lbs/gal

9.55

Freeze Point

+8°F

20 wt%

Specific Gravity

1.189

lbs/gal

9.88

Freeze Point

-4°F

24 wt%

Specific Gravity

1.228

lbs/gal

10.20

Freeze Point

-20°F

28 wt%

Specific Gravity

1.275

lbs/gal

10.60

Freeze Point

-46°F

32 wt%

Specific Gravity

1.322

lbs/gal

10.99

Freeze Point

17°F

OxyChem Calcium Chloride - FAQs - Frequently Asked Questions

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